Aluminum Chemical Conversion Coating (Chrome-Free and Trivalent Chromium)
Aluminum Chemical Conversion Coating (Chrome-Free and Trivalent Chromium)
Aluminum chemical conversion coating (chrome-free and trivalent chromium) forms a dense inorganic film on the aluminum surface, greatly improving corrosion resistance. The resulting film has excellent adhesion with paint and adhesives, ensuring long-term durability. As an environmentally friendly alternative to conventional hexavalent chromium treatment, it is widely used in fields such as aerospace, transportation equipment, and electronics.
Reaction Formulas for Aluminum Chemical Conversion Coating (Chrome-Free and Trivalent Chromium)
| Chrome-Free (Zr-based) | Trivalent Chromium |
|---|---|
|
Self-oxidation of aluminum Al → Al³⁺ + 3e⁻ |
Self-oxidation of aluminum Al → Al³⁺ + 3e⁻ |
|
Formation of zirconium oxide film Al + Zr⁴⁺ + H₂O → Al–O–Zr + H₂↑ |
Formation of trivalent chromium film Cr³⁺ + 3OH⁻ → Cr(OH)₃ |
Characteristics of Aluminum Chemical Conversion Coating (Chrome-Free and Trivalent Chromium)
Aluminum chemical conversion coating forms a dense film on the aluminum surface through a chemical reaction, improving corrosion resistance, paint adhesion, and conductivity. Both environmentally friendly chrome-free and trivalent chromium treatments are available, and the process is adopted in fields requiring high reliability such as aerospace, transportation, and electronics.
| 1. Forms a strong, uniform oxide film on the aluminum surface that effectively prevents corrosion and maintains performance over long-term use. |
| 2. Improves adhesion with paints and adhesives, preventing peeling and bonding failures. |
| 3. Offers a choice between chrome-free treatment (no hexavalent chromium) and low-electrical-resistance trivalent chromium treatment, accommodating applications that require conductivity. |
Types of Aluminum Chemical Conversion Coating (Chrome-Free and Trivalent Chromium)
| Type | Characteristics |
|---|---|
| Trivalent Chromium Conversion Coating | Forms a film using trivalent chromium compounds without hexavalent chromium. Excellent corrosion resistance and paint adhesion; also suitable for applications requiring low-resistance conductivity |
| Chrome-Free Conversion Coating | Contains no chromium at all; forms a film using titanium or zirconium compounds. A thin film of about 100nm ensures corrosion resistance and paint adhesion. Compliant with environmental regulations (RoHS). |
Equipment and Available Sizes for Aluminum Chemical Conversion Coating (Chrome-Free and Trivalent Chromium)
| Manual Line | |||
|---|---|---|---|
| Size | 400×400×800[mm] | ||
| Weight | 10[kg] *Figures are for reference only — please contact us for details. | ||
*Jigs and treatment tanks can be custom-made in-house by our maintenance department. We can also accommodate rush jig requirements.
Advantages and Disadvantages of Aluminum Chemical Conversion Coating (Chrome-Free and Trivalent Chromium)
| Advantages | ・Greatly improves adhesion as a base for painting or bonding ・Combines corrosion resistance with environmental friendliness ・Adopted in high-reliability applications such as aerospace and electronics |
|---|---|
| Disadvantages | ・The film is thin and, on its own, not suited to high-durability applications ・Chrome-free coatings in particular are sensitive to process conditions and require careful control ・Uneven processing or color variation may occur depending on the base material |
Film Properties of Aluminum Chemical Conversion Coating (Chrome-Free and Trivalent Chromium)
| Property | Chrome-Free (Zr-based) Trivalent Chromium |
|---|---|
| Structure | Zr oxide + Al oxide layer Cr(III) compound + Al oxide layer |
| Corrosion Resistance | Corrosion resistant Higher corrosion resistance than chrome-free |
| Film Thickness | Very thin (tens to a few hundred micrometers) |
| Adhesion | Well suited as a paint base, with good paint adhesion |
| Appearance | Colorless film Base material color to pale milky white |
Compatible Materials
Aluminum in general
Applications and Case Examples of Aluminum Chemical Conversion Coating (Chrome-Free and Trivalent Chromium)
Aircraft
Electrical Components
表面処理や鍍金加工に限らず、実現したいことや困りごと、どんなことでも相談してください。
試作品や、1点のみのご依頼にも柔軟に対応いたします。